I agree with the sentiment that a lot depends on your location. Well water can be good sometimes but it can be bad sometimes, it all depends on what's getting into the source of that well. Unfortunately there have been wells that were once good but then became contaminated by manufactures dumping toxic chemicals that eventually find their way into the source a well taps into. City treated tap water can likewise be decent enough to use if the source of that water is relatively clean and doesn't require a bunch of things added to clean up the water to make it drinkable. Rainwater is the same, since it gets up into the air it's mostly cleaned by nature and the evaporation process the concern is more about what else is getting into that air and what it has to pass thru on it's way down, if you live in the country or more rural locations your rainwater is probably mostly okay, it may have picked up some contaminants along the way but they likely are at a low level. The real worry is if your rain is falling in a heavily industrialized area with manufacturing and chemical plants pumping lots of pollution in the air that the rain then has to fall thru. If you want to be sure there's absolutely no unwanted elements in your water then either use distilled water or an RO system. The thing is though, some of the stuff in water is good things like the various nutrients and minerals we feed our plants. If you start with pure H2O then you're probably going to need to add more of something, usually this ends up being calcium and magnesium, most other things come in sufficient quantities in the products we feed our plants but calcium and magnesium is something that few products have in sufficient quantities which is why so many end up using CalMag supplements. There was a time back in the early days of man when all rainwater was the best water to use but unfortunately mankind has disrupted the environment sufficiently over the years that you can't take that as a given for all areas like you used to be able to do. It's still a good source though and usually better then treated tap water. I live in a small city which has no real manufacturing plants polluting the skies and I've had good success using rain water from time to time but I also have good well water and that's generally easier for me to use so that's what I use mostly.