Stan Laurel said:Just watered one of them through with rain water ph 7.4, runoff collected ph 6.78 ec 2.8
So, would that suggest it's not a lock out?
That is the one thing of this great hobby. There seems to be a whole lot of detective work with it. There is always a lot of ruling out to do to resolve a problem.
My last suggestions I was under the impression you were using RO water. My mistake I misread. Now you took this reading with rain water. It is in range, good. But have you been using the tap water as you posted in your initial post this whole time. That is what you need to use to get an accurate reading so you can figure out what has been happening this whole time. You have changed one of your constants to take this reading. It can throw off the whole process of elimination. Get an accurate run off reading with the tap water you have been using this whole time. If that is in range then suspect your tap water next which you said is hard. Give us an EC reading on that by itself. If it looks bad you may have to go RO water. If it seems ok then I would suspect a possible overfert. But again, I am familiar with the Bio Canna nutes and find them a little harder to burn with.