Gas exchange across a permeable membrane (including a meniscus) is determined by concentration gradients of the same gas, not the presence of other gases. The same amount of CO2 will pass out of or into solution irrespective of the presence of other gases in already in solution. The O2 - CO2 gas exchange isn't relevant I don't feel, as that generally refers (in my mind) to the O2 / CO2 binding to Hemoglobin.
A point that might help shed some light comes from the five basic postulates to the kinetic theory of gases:
•1. Gases consist of tiny molecular or atomic particles.
•2. The proportion between the size of these particles and the distances between them is so small that the individual particles can be assumed to have negligible volume.
•3. These particles experience continual random motion. When placed in a container, their collisions with the walls of the container constitute the pressure exerted by the gas.
•4. The particles neither attract nor repel one another.
•5. The average kinetic energy of the particles in a gas is directly related to absolute temperature.
Points #1 and #2 are the key. Dissolved gases essentially add no volume to the solute, so one gas doesn't have to leave in order to "make room" for the another. Several gases can go into and out of the same solution independently, without any regard for the others because when in solution, there is a near-universe of space for these gases to fit. This presumes that the gases do not enter into chemical reactions with the water.
A point that might help shed some light comes from the five basic postulates to the kinetic theory of gases:
•1. Gases consist of tiny molecular or atomic particles.
•2. The proportion between the size of these particles and the distances between them is so small that the individual particles can be assumed to have negligible volume.
•3. These particles experience continual random motion. When placed in a container, their collisions with the walls of the container constitute the pressure exerted by the gas.
•4. The particles neither attract nor repel one another.
•5. The average kinetic energy of the particles in a gas is directly related to absolute temperature.
Points #1 and #2 are the key. Dissolved gases essentially add no volume to the solute, so one gas doesn't have to leave in order to "make room" for the another. Several gases can go into and out of the same solution independently, without any regard for the others because when in solution, there is a near-universe of space for these gases to fit. This presumes that the gases do not enter into chemical reactions with the water.