My experience is, synthetic sourced Si (Potassium Silicate) will usually have a higher ratio of Plant Available Silica:Available Silica, but synthetic sourced Si is also absorbed by the plant in greater amounts (based on tissue analysis). A common characteristic that most synthetic nutrients have.
Whereas plants treated with food grade Diatomaceous Earth (non-synthetic source of Silica) contained slightly lower levels of SI, but still substantial amounts of PAS. But peculiar to food grade DE, analysis indicated there were also greater levels of plant available calcium, magnesium, phosphorus and potassium (something that plants treated with Potassium Silicate did not indicate). Nice bonus--a simple symmetry between DE and Ca, Mg, P, & K allows me to use less without any sacrifice.
Whereas plants treated with food grade Diatomaceous Earth (non-synthetic source of Silica) contained slightly lower levels of SI, but still substantial amounts of PAS. But peculiar to food grade DE, analysis indicated there were also greater levels of plant available calcium, magnesium, phosphorus and potassium (something that plants treated with Potassium Silicate did not indicate). Nice bonus--a simple symmetry between DE and Ca, Mg, P, & K allows me to use less without any sacrifice.