0.21 kPa is so bad for plants it should be off the chart, mate. Also, 5 deg. C diference from air to leaf temp is a lot. You either had temp fluctuations just before measuring, or the plants were transpiring too much, cooling the leaf surface considerably more. A stable environment with good VPD usually means the leaf and air temps are closer, as you can see that website uses a 2 deg. C diference to base the calculations on. That is about as much of a diference as I would expect in a stable environment with proper VPD.
There is no point in me linking a VPD chart now, the app on that website that has been linked seems much better and easier to follow.
It all depends... suppressing power generates heat.
This is the chart I use.
The RH is set with a humidity controller, it's on all the time (on/off) by itself as needed. I'm in my last 3 weeks and I am currently running my set up @ 75 degF and 55%. Night time temps come out at 67/68 deg 55% (winter here). During the early grow stage, my temps are 78/79 deg and 68 deg lights out (ambient temp is 70). I tweak (fine tune) using my exhaust fan speed.
I start them off @ 70% RH and will lower as I go, when "the" number is no longer achievable (hard to maintain) for the stage I am in. In other words... when "auto" (me) gets tired of tweaking to achieve desired VPD.
That being said, because our weather pattern in the Maritimes is simply too "helter skelter" during the summer, I forgo growing from end May to end of Aug. Fall run (end Aug - end Dec) Winter run (end Dec - mid/end May). YMMV! This is what works for me with my local weather pattern. Hope it helps