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Understanding terpenes and their relationship to growing conditions.

Verdant Whisperer

Well-known member

Main Terpenes and Their Roles in Cannabis Plants: A Breeding Approach


Understanding Terpenes and Their Roles in Cannabis

Terpenes are essential for the survival and adaptability of cannabis plants, influencing their aroma, flavor, defense mechanisms, and environmental resilience. By understanding how terpenes relate to environmental factors, breeders can better target specific terpene profiles in their plants for desired effects.


Environmental Influence on Terpenes

Different environmental factors—such as climate, altitude, humidity, and soil—directly affect terpene production. Understanding these influences allows breeders to reproduce specific conditions to achieve desired terpene outcomes.

Terpene Profile Groups

By grouping landraces according to their dominant-to-tertiary terpene profiles, breeders can better understand how a plant’s environment influences its terpene makeup. This helps guide breeding programs aimed at specific terpene profiles.


Synergistic Breeding for Desired Effects

Analyzing terpene profiles and replicating the environmental conditions that promote specific terpenes enables breeders to create F1 hybrids with targeted effects. This strategy allows for more purposeful breeding and eliminates reliance on randomness.


Core Terpenes and Their Environmental Roles

UV Protection: Limonene and Nerol

  • Limonene:
    • Environmental Association: Found in warm, sunny climates with high UV exposure.
    • Role: Limonene serves as a UV shield, providing antioxidant and insect-repellent properties. It is ideal for plants in hot, sunny environments.
  • Nerol:
    • Environmental Association: Found in cooler climates with fluctuating temperatures and humidity.
    • Role: Nerol offers UV protection, resilience to cold stress, and antifungal and antibacterial benefits in humid environments.

Humidity Shields: Alpha-Pinene and Beta-Pinene

  • Alpha-Pinene:
    • Environmental Association: Found in humid environments.
    • Role: Alpha-pinene prevents excessive moisture absorption by forming a protective layer that reduces mold and mildew risks while promoting growth.
  • Beta-Pinene:
    • Environmental Association: Common in drier, arid climates.
    • Role: Beta-pinene helps retain moisture and supports hydration, making it essential for plants in dry environments.

Altitude-Dependent Terpenes: Terpinolene and Ocimene

  • Terpinolene:
    • Environmental Association: More concentrated in high-altitude, dry environments.
    • Role: Terpinolene provides UV protection, helps with cold stress, and acts as an insect repellent.
  • Ocimene:
    • Environmental Association: Found in low-altitude, wetter environments.
    • Role: Ocimene helps manage humidity and offers antifungal and insect-repellent properties.

Myrcene and Its Relationship with Latitude and Light

Myrcene is crucial for how cannabis plants adapt to different latitudes and light cycles. Plants grown farther from the equator tend to have higher myrcene concentrations due to increased light variability and seasonal changes.

  • Myrcene and Latitude: Cannabis strains grown at higher latitudes produce more myrcene to adapt to greater variability in light and seasons.
  • Indoor Growth: Plants grown indoors under controlled light cycles show increased myrcene production as a response to regulated light changes.

Alpha vs. Beta Myrcene in Cannabis

The expression of alpha- and beta-myrcene is determined by environmental factors. These two forms of myrcene impact the plant’s aroma, effects, and adaptability to its environment.

Key Factors Influencing Alpha and Beta Myrcene Expression:​

  1. Watering and Hydration:
    • Alpha-Myrcene: Regular watering encourages alpha-myrcene production, leading to sweet and fruity aromas.
    • Beta-Myrcene: Drought conditions lead to more beta-myrcene, which has an earthy, musky profile as a defense mechanism.
  2. Soil Composition:
    • Alpha-Myrcene: Nutrient-rich soil promotes sweet, fruity alpha-myrcene.
    • Beta-Myrcene: Nutrient-poor soil increases the production of earthy beta-myrcene as the plant adapts to stress.
  3. Light Exposure:
    • Alpha-Myrcene: Full sunlight promotes the production of alpha-myrcene, contributing to sweet aromas.
    • Beta-Myrcene: In lower light, plants produce more beta-myrcene, resulting in earthy, herbal aromas.
  4. Climate and Temperature:
    • Alpha-Myrcene: Warm climates encourage alpha-myrcene, which produces sweet, uplifting aromas.
    • Beta-Myrcene: Cooler climates favor the production of beta-myrcene, which has a grounding, earthy aroma.
  5. Humidity:
    • Alpha-Myrcene: High humidity encourages alpha-myrcene production.
    • Beta-Myrcene: Low humidity results in beta-myrcene, as the plant conserves moisture in dry conditions.

Beta-Caryophyllene (BCP): A Growth Regulator in Low-Light/Humid Environments

Beta-Caryophyllene (BCP) is an essential growth regulator, particularly in low-light conditions. It helps the plant conserve energy by slowing growth and focusing on survival.

  • In Low-Light: BCP slows plant growth, allowing it to conserve resources.
  • Sunlight Availability: BCP increases in low-sunlight environments, resulting in smaller, more efficient plants.
  • Longer-Flowering Strains: BCP is vital for longer-flowering strains, helping the plant endure moisture fluctuations and pathogen threats during extended flowering cycles.
  • Shorter-Flowering Strains: BCP plays a smaller role in shorter-flowering plants, which prioritize rapid growth and defense.

Cannabinoids and Sesquiterpenes as Growth Regulators

  • THC: THC helps regulate plant growth by directing energy toward trichome production rather than plant size. High-THC plants are often smaller but more resilient to environmental stresses like UV radiation and drought.
  • Sesquiterpenes: Compounds such as beta-caryophyllene and humulene help regulate plant growth in low-light or nutrient-poor environments, allowing the plant to focus on long-term defense.

Why Monoterpene- and Sesquiterpene-Dominant Plants Coexist in Fields

Monoterpene- and sesquiterpene-dominant plants often coexist in the same environment due to their different growth rates and light needs.

  • Monoterpene-Dominant Plants (e.g., Limonene, Alpha-Myrcene): These fast-growing plants thrive in full sunlight, producing lighter terpenes.
  • Sesquiterpene-Dominant Plants (e.g., Beta-Caryophyllene, Beta-Myrcene): These slower-growing plants do well in shaded areas, producing heavier sesquiterpenes to cope with long-term stress.

Breeding for Latitude Compatibility

Breeding for specific latitudes requires selecting strains adapted to different environmental conditions. By crossing strains from Uganda (0° latitude) and Kashmir (34° latitude), for example, hybrids can be produced that thrive at mid-latitudes (~17° latitude), optimizing traits like day length adaptation, growth cycles, and terpene production.


Spiciness and Growth Regulation

Strains high in THCV or grown in dry regions with low humidity often exhibit a spicier taste. This spiciness is linked to how cannabis regulates growth in response to environmental stressors like shade or drought.


Geraniol and Linalool: Defense Terpenes and Environmental Adaptations

Both geraniol and linalool serve key roles in plant defense but are associated with different environments:

  • Geraniol (NLD Association):
    Found in warm, humid regions, it serves as an insect repellent and antifungal agent.
  • Linalool (BLD Association):
    Found in cold, high-altitude regions, it provides antifungal and antimicrobial effects while helping plants handle cold stress.
 

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Creeperpark

Well-known member
Mentor
Veteran

Main Terpenes and Their Roles in Cannabis Plants: A Breeding Approach

To explain my breeding style, I focus on the core terpenes and how they relate to the plant’s environment. By leveraging these factors, I aim to enhance synergistic breeding for specific effects. Here’s how I break it down:


Understanding Terpenes and Their Roles in Plants

Terpenes are vital to cannabis plants, influencing aroma, flavor, defense, and environmental adaptation. Each terpene dominates specific strains due to environmental pressures, helping the plant survive and thrive in various conditions.


Environmental and Soil Influence on Terpenes

Different climates and soil types directly affect terpene production in cannabis. By understanding why certain terpenes dominate in specific regions, we can strategically breed plants with desired terpene profiles.


Terpene Profile Groups

By grouping landraces based on their dominant-to-tertiary terpene profiles, we can explore the relationship between a strain’s terroir (climate and environment) and its resulting terpene makeup.


Synergistic Breeding for Desired Effects

When breeding for specific terpene outcomes, analyzing terpene profiles and replicating the environmental conditions that produce those outcomes enables us to breed with purpose. This allows for specific effects in F1 hybrids without relying on luck.


Core Terpenes: Roles and Environmental Associations

UV Protection: Terpenes and Their Environmental Roles

Plants produce terpenes to protect themselves from harmful UV radiation. Two key terpenes involved in this process are limonene and nerol:

  • Limonene:
    • Found in warm climates with high UV exposure.
    • Acts as a direct UV shield.
    • Suited for sunny, hot environments.
    • Provides insect-repellent and antioxidant properties.
  • Nerol:
    • Found in cooler climates with fluctuating temperatures.
    • Provides UV protection and cold stress resilience.
    • Ideal for humid environments with fungal risks.
    • Offers antifungal and antibacterial benefits.

Alpha-Pinene: Humidity Shield

  • Role: Alpha-pinene acts as a humidity shield, preventing excessive moisture absorption.
  • How it works: Forms a protective layer on the plant’s surface, reducing mold and mildew risks while aiding growth in humid environments.

Beta-Pinene: Humidity Aid

  • Role: Beta-pinene helps plants in drier environments by aiding moisture absorption.
  • How it works: It supports plants in arid regions by retaining moisture and promoting hydration.

Terpinolene and Ocimene: Altitude-Dependent Terpenes

These terpenes are adapted to specific altitudes and moisture levels:

  • Terpinolene:
    • More concentrated in high-altitude, dry environments.
    • Offers UV protection and helps with cold stress and insect repelling.
  • Ocimene:
    • More concentrated in low-altitude, wetter environments.
    • Helps manage humidity and provides antifungal and insect-repellent properties.

Myrcene and Its Relationship with Latitude and Light

Myrcene plays a major role in how cannabis plants respond to latitude and light cycles:

  • Myrcene and Latitude:
    Strains grown further from the equator tend to have higher myrcene concentrations due to greater light variability and seasonal changes.
  • Myrcene in Indoor Growth:
    Plants grown indoors under controlled light cycles also show increased myrcene production due to the regulated light changes.

Beta-Caryophyllene (BCP): Growth Regulator in Low-Light Environments

Beta-Caryophyllene (BCP) helps regulate growth, particularly in low-light conditions. It conserves energy, ensuring the plant uses its resources efficiently:

  • In Low-Light: BCP helps the plant slow its growth and focus on survival rather than rapid expansion.
  • Sunlight Availability: BCP increases in low-sunlight environments, resulting in smaller, more efficient plants.
  • BCP and Longer Flowering Strains

    BCP plays a key role in longer-flowering cannabis varieties by aiding in plant preservation throughout extended flowering cycles. It slows growth and focuses on defense, allowing the plant to withstand environmental stresses like pathogens and moisture fluctuations over time.

    In long-flowering strains, the plant faces increased vulnerability to these stresses, and BCP helps by promoting steady growth, ensuring the plant remains healthy during the entire cycle. This is particularly important in low-light or humid environments, where plants must defend against fungal or bacterial threats for extended periods.

    BCP in Short-Flowering Strains

    In shorter-flowering varieties, BCP is less dominant because the plant’s needs shift to rapid development and quick defense mechanisms, relying more on other terpenes that offer faster protection against environmental threats. As a result, BCP plays a smaller role in such varieties, especially in full-sun environments where the plant's lifecycle is shorter.

Spiciness and Growth Regulation

Strains high in THCV or grown in dry regions with low humidity often exhibit a spicier taste. This spiciness is linked to how cannabis regulates growth in response to environmental stressors like shade or drought.


Geraniol and Linalool: Defense Terpenes and Environmental Adaptations

Both geraniol and linalool serve key roles in plant defense but are associated with different environments:

  • Geraniol (NLD Association):
    Found in warm, humid regions, it serves as an insect repellent and antifungal agent.
  • Linalool (BLD Association):
    Found in cold, high-altitude regions, it provides antifungal and antimicrobial effects while helping plants handle cold stress.

Cannabinoids and Sesquiterpenes as Growth Regulators

Cannabinoids like THC and sesquiterpenes such as beta-caryophyllene and humulene act as growth regulators. In low light, shade, or resource-limited conditions, these compounds help the plant slow its growth and focus on survival.


THC and Growth Regulation

THC helps plants focus their energy on trichome production (rich in cannabinoids) rather than size, leading to smaller, more resilient plants that excel in high-UV or arid environments.


Sesquiterpenes as Growth Regulators

Beta-caryophyllene and humulene help plants manage growth in low-light or nutrient-poor environments. These heavier terpenes require more energy to produce, but they are crucial for long-term defense.


Why Monoterpene-Dominant and Sesquiterpene-Dominant Plants Coexist in Fields

The coexistence of monoterpene-dominant and sesquiterpene-dominant plants in the same field is due to growth rates and light availability:

  • Monoterpene-Dominant Plants (Fast-Growing, Sun-Loving):
    Grow quickly, produce lighter monoterpenes, and absorb more sunlight. Their growth creates shade for smaller plants.
  • Sesquiterpene-Dominant Plants (Slower-Growing, Shade-Tolerant):
    Thrive in shady environments and focus on producing heavier sesquiterpenes to cope with low light and long-term stress.
This balance allows sun-exposed plants to produce monoterpenes, while shaded plants focus on sesquiterpenes, resulting in a diverse terpene profile within the same crop.

View attachment 19078554
That is amazing information and very helpful. Thanks for posting friend.
 

Prs2xs

Active member

Main Terpenes and Their Roles in Cannabis Plants: A Breeding Approach

To explain my breeding style, I focus on the core terpenes and how they relate to the plant’s environment. By leveraging these factors, I aim to enhance synergistic breeding for specific effects. Here’s how I break it down:


Understanding Terpenes and Their Roles in Plants

Terpenes are vital to cannabis plants, influencing aroma, flavor, defense, and environmental adaptation. Each terpene dominates specific strains due to environmental pressures, helping the plant survive and thrive in various conditions.


Environmental and Soil Influence on Terpenes

Different climates and soil types directly affect terpene production in cannabis. By understanding why certain terpenes dominate in specific regions, we can strategically breed plants with desired terpene profiles.


Terpene Profile Groups

By grouping landraces based on their dominant-to-tertiary terpene profiles, we can explore the relationship between a strain’s terroir (climate and environment) and its resulting terpene makeup.


Synergistic Breeding for Desired Effects

When breeding for specific terpene outcomes, analyzing terpene profiles and replicating the environmental conditions that produce those outcomes enables us to breed with purpose. This allows for specific effects in F1 hybrids without relying on luck.


Core Terpenes: Roles and Environmental Associations

UV Protection: Terpenes and Their Environmental Roles

Plants produce terpenes to protect themselves from harmful UV radiation. Two key terpenes involved in this process are limonene and nerol:

  • Limonene:
    • Found in warm climates with high UV exposure.
    • Acts as a direct UV shield.
    • Suited for sunny, hot environments.
    • Provides insect-repellent and antioxidant properties.
  • Nerol:
    • Found in cooler climates with fluctuating temperatures.
    • Provides UV protection and cold stress resilience.
    • Ideal for humid environments with fungal risks.
    • Offers antifungal and antibacterial benefits.

Alpha-Pinene: Humidity Shield

  • Role: Alpha-pinene acts as a humidity shield, preventing excessive moisture absorption.
  • How it works: Forms a protective layer on the plant’s surface, reducing mold and mildew risks while aiding growth in humid environments.

Beta-Pinene: Humidity Aid

  • Role: Beta-pinene helps plants in drier environments by aiding moisture absorption.
  • How it works: It supports plants in arid regions by retaining moisture and promoting hydration.

Terpinolene and Ocimene: Altitude-Dependent Terpenes

These terpenes are adapted to specific altitudes and moisture levels:

  • Terpinolene:
    • More concentrated in high-altitude, dry environments.
    • Offers UV protection and helps with cold stress and insect repelling.
  • Ocimene:
    • More concentrated in low-altitude, wetter environments.
    • Helps manage humidity and provides antifungal and insect-repellent properties.

Myrcene and Its Relationship with Latitude and Light

Myrcene plays a major role in how cannabis plants respond to latitude and light cycles:

  • Myrcene and Latitude:
    Strains grown further from the equator tend to have higher myrcene concentrations due to greater light variability and seasonal changes.
  • Myrcene in Indoor Growth:
    Plants grown indoors under controlled light cycles also show increased myrcene production due to the regulated light changes.

Beta-Caryophyllene (BCP): Growth Regulator in Low-Light Environments

Beta-Caryophyllene (BCP) helps regulate growth, particularly in low-light conditions. It conserves energy, ensuring the plant uses its resources efficiently:

  • In Low-Light: BCP helps the plant slow its growth and focus on survival rather than rapid expansion.
  • Sunlight Availability: BCP increases in low-sunlight environments, resulting in smaller, more efficient plants.
  • BCP and Longer Flowering Strains

    BCP plays a key role in longer-flowering cannabis varieties by aiding in plant preservation throughout extended flowering cycles. It slows growth and focuses on defense, allowing the plant to withstand environmental stresses like pathogens and moisture fluctuations over time.

    In long-flowering strains, the plant faces increased vulnerability to these stresses, and BCP helps by promoting steady growth, ensuring the plant remains healthy during the entire cycle. This is particularly important in low-light or humid environments, where plants must defend against fungal or bacterial threats for extended periods.

    BCP in Short-Flowering Strains

    In shorter-flowering varieties, BCP is less dominant because the plant’s needs shift to rapid development and quick defense mechanisms, relying more on other terpenes that offer faster protection against environmental threats. As a result, BCP plays a smaller role in such varieties, especially in full-sun environments where the plant's lifecycle is shorter.

Spiciness and Growth Regulation

Strains high in THCV or grown in dry regions with low humidity often exhibit a spicier taste. This spiciness is linked to how cannabis regulates growth in response to environmental stressors like shade or drought.


Geraniol and Linalool: Defense Terpenes and Environmental Adaptations

Both geraniol and linalool serve key roles in plant defense but are associated with different environments:

  • Geraniol (NLD Association):
    Found in warm, humid regions, it serves as an insect repellent and antifungal agent.
  • Linalool (BLD Association):
    Found in cold, high-altitude regions, it provides antifungal and antimicrobial effects while helping plants handle cold stress.

Cannabinoids and Sesquiterpenes as Growth Regulators

Cannabinoids like THC and sesquiterpenes such as beta-caryophyllene and humulene act as growth regulators. In low light, shade, or resource-limited conditions, these compounds help the plant slow its growth and focus on survival.


THC and Growth Regulation

THC helps plants focus their energy on trichome production (rich in cannabinoids) rather than size, leading to smaller, more resilient plants that excel in high-UV or arid environments.


Sesquiterpenes as Growth Regulators

Beta-caryophyllene and humulene help plants manage growth in low-light or nutrient-poor environments. These heavier terpenes require more energy to produce, but they are crucial for long-term defense.


Why Monoterpene-Dominant and Sesquiterpene-Dominant Plants Coexist in Fields

The coexistence of monoterpene-dominant and sesquiterpene-dominant plants in the same field is due to growth rates and light availability: *This is seen in fields with high density planting where it creates shaded environments for the less vigourous phenotypes. a good example of this is malawi gold from malawi it has spicy herbal and sour pineapple phenotypes and is grown in dense fields,

  • Monoterpene-Dominant Plants (Fast-Growing, Sun-Loving):
    Grow quickly, produce lighter monoterpenes, and absorb more sunlight. Their growth creates shade for smaller plants.
  • Sesquiterpene-Dominant Plants (Slower-Growing, Shade-Tolerant):
    Thrive in shady environments and focus on producing heavier sesquiterpenes to cope with low light and long-term stress.
This balance allows sun-exposed plants to produce monoterpenes, while shaded plants focus on sesquiterpenes, resulting in a diverse terpene profile within the same crop.

View attachment 19078554

The Sweet vs. Earthy Expression of Myrcene in Cannabis: A Detailed Exploration

Our discussion about myrcene in cannabis has revealed a fascinating insight: the environment plays a crucial role in how myrcene expresses itself, not just in aroma and flavor but also in effects. This complex interaction between genetics and growing conditions offers a deeper understanding of why myrcene can sometimes exhibit a sweet, fruity profile with uplifting effects, while at other times it takes on a more earthy, grounded aroma with sedative effects.

What is Myrcene?

Myrcene is one of the most abundant terpenes found in cannabis, contributing to the fruity, herbal, and earthy aromas often associated with various strains. It's known for its calming, sedative effects, but as we discussed, the specific aroma and effect profile can change depending on several environmental and cultivation factors.

Environmental Factors Influencing Myrcene Expression

Based on our conversation, here are the key factors that seem to influence whether myrcene exhibits a sweet or earthy profile:

1. Watering and Hydration

  • Manual Watering: When plants are consistently manually watered, they tend to produce sweeter, more fruity expressions of myrcene. The plant isn’t stressed by drought, so it can allocate energy to producing sweet, fragrant terpenes that contribute to an uplifting effect.
  • Drought Stress: In fields without additional watering, cannabis plants experience mild water stress, which can push them to produce earthier, muskier myrcene. This shift is a defense mechanism, helping the plant survive under less favorable conditions. The resulting terpene profile is often more grounded, herbal, and sedative.

2. Soil Composition and Nutrients

The nutrient composition of the soil also plays a role in how myrcene expresses itself. Nutrient-rich soil, full of organic matter, tends to promote sweet, fruity terpene profiles. In contrast, poorer, more compact soil might push the plant toward earthier expressions of myrcene. When the plant is under nutrient stress, its terpene production leans more toward earthy, herbal notes as it adjusts to the lack of optimal resources.

3. Light Exposure

The amount of sunlight and the intensity of UV exposure can influence terpene production:

  • Full Sunlight: Under strong, consistent light, cannabis plants often produce more sweet and fruity aromas, including the sweeter form of myrcene. This might be due to the plant’s ability to photosynthesize more efficiently in these conditions, leading to a healthier terpene profile.
  • Shady or Low-Light Conditions: In environments with less light, plants tend to produce earthier, herbal terpenes as they adapt to lower energy levels. This could explain why earthy myrcene is more prevalent in shadier or high-altitude environments.

4. Climate and Temperature

Temperature has a significant impact on terpene expression:

  • Warmer Climates: Sweet myrcene is often associated with warm, tropical climates, where cannabis thrives and can express more uplifting, fruity terpenes. The plant is less stressed and can focus more on developing a sweet, pleasant aroma.
  • Cooler or Harsher Climates: In colder regions or places with more extreme temperature shifts, myrcene often expresses as earthy or musky, reflecting the plant’s adaptation to a tougher growing environment. This version of myrcene is typically more grounding and sedative.

5. Humidity

  • High Humidity: Myrcene in more humid environments tends to be sweeter, reflecting the plant’s easier access to water and less need for defense against environmental stressors.
  • Low Humidity: In dry climates, myrcene can take on an earthier profile. Dry conditions put stress on the plant, and it may produce terpenes that are more protective and earthy to cope with the lack of moisture.

6. Terpene Interactions

Myrcene does not work in isolation; it interacts with other terpenes in the plant. For instance:

  • When myrcene is present alongside limonene or geraniol, it tends to express more sweet, fruity notes, contributing to uplifting effects.
  • However, when beta-caryophyllene or pinene are more dominant, myrcene may lean toward earthy or herbal tones, giving the strain a more grounding, sedative quality.

7. Stress from Pests, Pathogens, or Physical Damage

Plants exposed to pests or diseases tend to produce more earthy terpenes, including myrcene, as part of their defense mechanism. These stressors push the plant to focus on survival, shifting the terpene profile toward earthier, protective aromas.

Sweet vs. Earthy Myrcene: How the Effects Change

What makes this all the more fascinating is how the aroma and flavor profile of myrcene correlates with its effects:

  • Sweet Myrcene: When myrcene is expressed as sweet and fruity, it tends to have more uplifting, energizing effects. This version of myrcene is ideal for users seeking creativity, focus, and social energy.
  • Earthy Myrcene: In contrast, earthy myrcene typically promotes calming, grounding, and sedative effects. This version is better suited for relaxation, stress relief, and sleep.

Conclusion: Why Environment Matters

The way myrcene expresses itself as either sweet or earthy is a reflection of how the plant adapts to its environment. Factors like watering practices, soil quality, light exposure, and stress can all influence whether myrcene takes on a more uplifting, fruity profile or a grounding, earthy one. This insight underscores the importance of understanding the interplay between environment and genetics when cultivating cannabis for specific effects.

By optimizing these environmental factors, growers can fine-tune myrcene expression to suit their desired outcomes, whether it’s producing strains with uplifting, sweet aromas or earthy, calming effects.

Breeding for Latitude Compatibility​

An essential aspect of my breeding strategy is understanding how latitude affects cannabis plants. When selecting parent strains, I focus on balancing environmental traits from regions with different latitudes to create hybrids that are well-suited for specific climates.

For example, I combine strains from Uganda (0° latitude) and Kashmir (34° latitude) to produce hybrids that find a middle ground, around 17° latitude. This approach allows me to match the characteristics of plants adapted to different climates, ensuring that the resulting hybrids can thrive in areas with similar environmental conditions, such as sunlight intensity, day length, and humidity levels.

By balancing parental genetics based on latitude, I optimize not only the terpene profiles but also the plant's resilience to the growing environment. This method showcases how understanding environmental factors and strategic breeding can result in robust hybrids adapted to their specific conditions.
This is very interesting. Regarding point #7, I wonder if the use of "chitosal" ( a product which is supposed to give the plant systemic resistance to pests and pathogens} would cause a shift in the terpene profile to the earthy type?? I may try using it on only one plant in the future to see if this is the case!
 

Verdant Whisperer

Well-known member
This is very interesting. Regarding point #7, I wonder if the use of "chitosal" ( a product which is supposed to give the plant systemic resistance to pests and pathogens} would cause a shift in the terpene profile to the earthy type?? I may try using it on only one plant in the future to see if this is the case!
Its possible I've heard that high amounts of chitosan in the soil are supposed to trick the plant into thinking theres alot of bugs, but I don't know if the plants are that dumb honestly. they are smart and efficient they know what bugs attack them and mess with their roots and make specific chemicals for them. its possible thought im not sure but the more i learn about the plants the smarter they seem.
 

nepalnt21

FRRRRRResh!
Veteran

Sweet vs. Earthy Myrcene: How the Effects Change

What makes this all the more fascinating is how the aroma and flavor profile of myrcene correlates with its effects:

  • Sweet Myrcene: When myrcene is expressed as sweet and fruity, it tends to have more uplifting, energizing effects. This version of myrcene is ideal for users seeking creativity, focus, and social energy.
  • Earthy Myrcene: In contrast, earthy myrcene typically promotes calming, grounding, and sedative effects. This version is better suited for relaxation, stress relief, and sleep.
i see what you mean by how the flavor and aroma change based upon the other terps etc. but this part on its own is misleading because beta myrcene is one compound and if it were to change through some chemical reaction, it would be a different compound.

this adds to my incredulity surrounding the supposed fx of myrcene... clearly (imo), the entourage effect (incl cannabinoids etc) seems to be more responsible for the overall effect (that and individual differences in users and even day to day).... so i internally roll my eyes when a budtender just regurgitates what the little wallet cards say the terps do.

myrcene is in high amounts (and sometimes nearly alone) in some of the most long flowering and famous/ notorious sativas and sativa dominant hybrids.

so i'm agreeing with you on how the various terps can change the whole aroma and apparently experience, i just also wanted to be pendantic about how myrcene is myrcene just like how water is water (in an ideal, pure setting)
 

Verdant Whisperer

Well-known member
i see what you mean by how the flavor and aroma change based upon the other terps etc. but this part on its own is misleading because beta myrcene is one compound and if it were to change through some chemical reaction, it would be a different compound.

this adds to my incredulity surrounding the supposed fx of myrcene... clearly (imo), the entourage effect (incl cannabinoids etc) seems to be more responsible for the overall effect (that and individual differences in users and even day to day).... so i internally roll my eyes when a budtender just regurgitates what the little wallet cards say the terps do.

myrcene is in high amounts (and sometimes nearly alone) in some of the most long flowering and famous/ notorious sativas and sativa dominant hybrids.

so i'm agreeing with you on how the various terps can change the whole aroma and apparently experience, i just also wanted to be pendantic about how myrcene is myrcene just like how water is water (in an ideal, pure setting)
Hey Nepalnt, I Agree yesterday when i was pondering this idea, I was thinking maybe there is two types of myrcene, like with pinene, yet we are unaware of the distinctions, but it does make more sense that the myrcene is more inlfluenced by the other terpenes. but i still wouldnt be surprised to find out one day if there was different form of myrcene, im not a chemist just a landrace fanatic whos put in some time and investigation. it is called beta-myrcene, its possible there is a alpha-myrcene we just dont know how to test for the difference? just a thought, good catch there it is a bit misleading if you agree there is only one type of myrcene but i just want to challenge that idea for a moment that there isn't just sh*ts and giggles. maybe there is a scientist who can test a sweet myrcene versus earthy in a advacned setting to spot any differences. Basically just because Alpha-Myrcene has been identified doesn't mean it doesn't exist.

Thinking about it more, if that where the case than there would be a type of myrcene more adapated for sativas Alpha-myrcene that would explain ace's oldtimeres haze and malawi, and another myrcene for colder regions and more BLD like beta-myrcene is could be we only know how to test for one form and all the test are concluded as beta-myrcene even if alpha-myrcene. because it hasn't been identified yet our instruments will interpret all the myrcene as beta. this makes more sense to me based on how the plants evolve. its just a theory. also possible its just the entourage with other terps. but you really sparked my interest bring that up about the long flowering sativas.
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Furthermore the same relation suspected in myrcene can be found in Pinene
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If this is true then it seems alpha and beta forms of the Isomers are influenced by environment and have opposite uses, this would align with the ideas of universal balance as well. I can find example in other alpha and beta terpenes as well that fit this theory.
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Verdant Whisperer

Well-known member
So i loaded all my research into chap Gpt Premium version, and asked it to try and group the other main terpenes based on the previous information. I am not 100% sure about these but its just to give an idea.

To theorize about the uses of terpenes not mentioned in the original list based on their roles in cannabis plants and environmental interactions, let's explore the remaining key terpenes in relation to how they might assist the plant in thriving in various environmental conditions.

1. Camphene

  • Potential Role: Camphene has a sharp, musky scent similar to fir needles and might offer protection in cooler environments.
  • Environmental Association: Its antifungal and antimicrobial properties suggest it could be an important defense mechanism for cannabis plants in moist, humid climates where fungal infections are more common. Camphene may also help in cold stress resistance due to its presence in plants native to cooler regions.

2. Eucalyptol: Ex: Kilimanjaro, Panauti Village.

  • Potential Role: Known for its cooling, minty aroma, eucalyptol offers anti-inflammatory and insect-repellent properties.
  • Environmental Association: This terpene is typically associated with high-altitude and dry climates. Eucalyptol’s insect-repellent characteristics may help protect plants from pests in areas where the lack of moisture increases plant vulnerability.

3. Geraniol

  • Potential Role: Geraniol’s floral aroma has been associated with insect repellence and antifungal properties.
  • Environmental Association: Often found in tropical and subtropical strains, geraniol may be highly beneficial in warm, humid environments where the risk of fungal growth and insect attack is high. This terpene would thrive in regions where plant defense mechanisms must counter both pests and moisture-loving pathogens.

4. Fenchol

  • Potential Role: Fenchol offers antibacterial and antimicrobial benefits, helping to defend the plant.
  • Environmental Association: This terpene likely plays a role in humid, pathogen-prone environments. Its ability to fight off bacterial infections would be vital for plant survival, particularly in coastal or rainforest-like climates.

5. Sabinene

  • Potential Role: Known for its spicy, woody aroma, sabinene possesses antioxidant and antimicrobial properties.
  • Environmental Association: Sabinene might play a role in cannabis strains adapted to regions with fluctuating temperatures, helping protect against cold stress and supporting the plant’s immune system in harsh environments. Its antioxidant properties could aid in resilience against UV stress in high-altitude or highly sunny environments.

6. Nerolidol

  • Potential Role: With a floral, woody aroma, nerolidol is known for its antifungal, antiparasitic, and antioxidant properties.
  • Environmental Association: Nerolidol may protect cannabis plants in humid and warm climates where the risk of mold and parasitic threats is high. Its antioxidant properties suggest it might also help plants endure environmental stress from excessive sunlight or fluctuating temperatures.

7. Bisabolol

  • Potential Role: Known for its soothing properties, bisabolol has anti-inflammatory and antimicrobial benefits.
  • Environmental Association: This terpene may play a significant role in high-altitude or cooler regions where plants need enhanced resilience against environmental stressors, including cold and pathogens. Bisabolol’s calming properties may also support the plant during periods of environmental stress, helping to reduce the damage from oxidative stress and light exposure.

8. Borneol

  • Potential Role: Borneol’s minty aroma offers insect-repellent, anti-inflammatory, and analgesic properties.
  • Environmental Association: Borneol might be especially useful in tropical or high-insect-density areas, acting as a defense mechanism against pests. It may also help the plant manage oxidative stress in environments with strong sunlight or fluctuating temperatures.

 
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Sir this is a weed grower website. You can't tell weed growers that their weed smells like Glade plug-ins. They won't believe you. Or at least 30 years ago, people were smarter than that.

Do some actual weed-relevant terps. OG Kush terps maybe . Myrcenyl acetate. Limonyl acetate, linalyl acetate. Bornyl acetate. Shit that might possible smell like weed?

Why no talk about carboxylic acids. The forbidden topic. You know, the only important functional group of Cannabis metabolites. We still letting Kevin "DEA boof peddler" Jodrey and his flock of DEA pharma goons tell us Cheese should smell like carbolic acid and terpinolene instead of 3-methyl butanoic and methane thiol? That thc isolate gets you higher for more hours? Nothing these people say ads up yet there's always plenty of AI accounts pushing the same exact pharma narrative.

You can ignore at best, and add to your hitlist if you're proactive, the people claiming good weed smells like cough syrup,or that higher thc % has a longer duration between doses. The goal is obvious. When your favorite strains are characterized by DEA/pharma interlopers.

All the pharma spook misinfo in the Cannabis scene is just that, pharma spook misinfo. Couldn't beat us so they planted a bunch of spooks amongst us. Real breeders are actively removing the terps that cannabis labs test for from their gene pools. Everyone wondering where skunk went... While everyone's plants are wasting energy on useless dead weight terpenes that exist in everything from a piece of meat to a piece of plastic.

You're gonna make me post the test results for a piece of ham and a piece of a shower curtain material I sent for terpene analysis? I was saving that for later. Maybe tomorrow. Very terpy stuff. Although no one has ever smelled lemon from a shower curtain counting significant quantity of limonene, or a lavender from a piece of ham containing tons of linalool. Seems irrelevant, until you realise WHY the community is perpetually told the same lies over and over about what's relevant and what's not.
 

Verdant Whisperer

Well-known member
Sir this is a weed grower website. You can't tell weed growers that their weed smells like Glade plug-ins. They won't believe you. Or at least 30 years ago, people were smarter than that.

Do some actual weed-relevant terps. OG Kush terps maybe . Myrcenyl acetate. Limonyl acetate, linalyl acetate. Bornyl acetate. Shit that might possible smell like weed?

Why no talk about carboxylic acids. The forbidden topic. You know, the only important functional group of Cannabis metabolites. We still letting Kevin "DEA boof peddler" Jodrey and his flock of DEA pharma goons tell us Cheese should smell like carbolic acid and terpinolene instead of 3-methyl butanoic and methane thiol? That thc isolate gets you higher for more hours? Nothing these people say ads up yet there's always plenty of AI accounts pushing the same exact pharma narrative.

You can ignore at best, and add to your hitlist if you're proactive, the people claiming good weed smells like cough syrup,or that higher thc % has a longer duration between doses. The goal is obvious. When your favorite strains are characterized by DEA/pharma interlopers.

All the pharma spook misinfo in the Cannabis scene is just that, pharma spook misinfo. Couldn't beat us so they planted a bunch of spooks amongst us. Real breeders are actively removing the terps that cannabis labs test for from their gene pools. Everyone wondering where skunk went... While everyone's plants are wasting energy on useless dead weight terpenes that exist in everything from a piece of meat to a piece of plastic.

You're gonna make me post the test results for a piece of ham and a piece of a shower curtain material I sent for terpene analysis? I was saving that for later. Maybe tomorrow. Very terpy stuff. Although no one has ever smelled lemon from a shower curtain counting significant quantity of limonene, or a lavender from a piece of ham containing tons of linalool. Seems irrelevant, until you realise WHY the community is perpetually told the same lies over and over about what's relevant and what's not.
It sounds like you know alot about the compounds in cannabis, if your curious check out the thread, its just focused on finding out what the use of terpenes are in the plant so we can better assume what the profliles are of landraces, for breeding based on their climates and descriptions.
 

Verdant Whisperer

Well-known member
I was trying to figure out Lolab valley, Kashmir terpene profile and encountered that there is 2 types of limonene as well.

R-Limonene (D-Limonene)

  • Flavor/Aroma: Citrus, orange, and sweet.
  • Effects: Uplifting, energizing, and mood-enhancing. R-limonene tends to be more stimulating and euphoric, often used in strains that focus on positive mental states and stress relief.
  • Environmental Adaptation: Associated with sunny, dry environments with high UV exposure. Plants in these regions produce more R-limonene as a defense mechanism against the sun’s stress, offering antioxidant properties and insect-repellent effects.
  • Typical Regions: Found in Mediterranean climates, deserts, and regions with strong sun and low humidity like Southern Europe, parts of California, and the Middle East.

S-Limonene (L-Limonene)

  • Flavor/Aroma: Lemon, with sour or herbal undertones. Compared to R-limonene, S-limonene has a fresher, more complex aroma with a hint of herbal elements.
  • Effects: Calming, balanced, and less stimulating than R-limonene. It promotes mental clarity and a focused, relaxed state without the intense euphoria associated with R-limonene.
  • Environmental Adaptation: More common in humid environments or regions with moderate UV exposure. S-limonene helps plants manage moisture and offers antimicrobial and antifungal protection in these climates.
  • Typical Regions: Found in tropical and subtropical areas with high humidity, such as India, Southeast Asia, and humid forest regions.

Comparison of R-Limonene vs. S-Limonene:​

AspectR-Limonene (D-Limonene)S-Limonene (L-Limonene)
Flavor/AromaSweet, orange, citrusLemon, sour, herbal
EffectsEnergizing, uplifting, mood-enhancingCalming, balanced, focused
Environmental RoleAntioxidant, insect repellentAntimicrobial, antifungal, moisture management
Typical EnvironmentDry, sunny, high-UV environmentsHumid, moderate-UV environments
Common RegionsMediterranean, California, Middle EastSoutheast Asia, India, humid forests

Practical Implications in Breeding:​

  • R-Limonene: Ideal for cannabis strains grown in dry, sunny conditions. It offers UV protection, insect resistance, and an energizing high. Useful in regions with high UV exposure.
  • S-Limonene: Best suited for strains in humid environments with moderate sunlight. It provides antifungal properties and produces a calming, balanced effect, making it ideal for regions with high humidity.

Alpha and Beta Bisabolol:​

  • Alpha-Bisabolol: Often found in hot, humid climates, it has a floral and sweet aroma with anti-inflammatory and antimicrobial properties, providing resilience in environments prone to fungal threats.
  • Beta-Bisabolol: Less common, typically found in cooler, drier climates. It has similar properties but is more suited for low-humidity environments where fungal threats are minimal.

1. Alpha-Bisabolol:

  • Flavor/Aroma: Floral, sweet, and herbal, with subtle citrus and woody undertones. The scent is often compared to chamomile, as alpha-bisabolol is a primary compound in German chamomile.
  • Effects: Alpha-bisabolol is known for its calming and soothing properties. It’s often associated with relaxation and anti-anxiety effects, making it common in strains used for stress relief and sleep support. It also has anti-inflammatory, antimicrobial, and antioxidant effects, which give it medicinal value in cannabis strains.
  • Environmental Adaptation: Alpha-bisabolol is well-suited for humid and moderate-to-warm climates. It’s highly resistant to fungal growth and offers antimicrobial properties, which help plants cope with humidity and pathogen-rich environments. It’s an ideal terpene for plants growing in tropical regions where mold and bacterial threats are common.
  • Typical Regions: Found in strains from humid environments, including tropical or subtropical regions. It's particularly useful in regions with moderate UV exposure and consistent moisture.

2. Beta-Bisabolol:

  • Flavor/Aroma: Woody and spicy with a more earthy character compared to the floral sweetness of alpha-bisabolol. It has a somewhat sharper scent, and the citrus notes are less prominent than in the alpha variant.
  • Effects: Beta-bisabolol has a calming effect but tends to be associated with a more grounding, warming, and mellow high. Like alpha-bisabolol, it also offers anti-inflammatory and antibacterial properties, but its effects are typically described as less soothing and more stabilizing in terms of mood and body relaxation.
  • Environmental Adaptation: Beta-bisabolol is often more prevalent in plants growing in drier, colder environments. It helps plants manage oxidative stress and offers protection against cold. Unlike alpha-bisabolol, beta-bisabolol tends to appear in strains that deal with more arid or cold conditions, offering resilience against cold stress and UV exposure.
  • Typical Regions: Found in plants adapted to dry, cooler climates or high-altitude environments. Regions with lower humidity and strong sunlight tend to favor beta-bisabolol production.

Summary of Differences:

AttributeAlpha-BisabololBeta-Bisabolol
Flavor/AromaFloral, sweet, citrus, herbal, chamomileWoody, spicy, earthy, subtle citrus
EffectsCalming, soothing, anti-anxietyGrounding, mellow, more stabilizing
Environmental RoleAntifungal, antimicrobial for humid climatesCold and UV protection in arid, colder regions
Common RegionsTropical or subtropical areas with high humidityDry, cool, or high-altitude climates

Practical Implications in Breeding:

  • Alpha-Bisabolol is perfect for breeding strains designed for humid and warm environments where fungal resistance and moisture management are important. The calming, soothing effects make it great for nighttime strains or strains aimed at relieving stress and inflammation.
  • Beta-Bisabolol, on the other hand, is more useful in colder or drier climates where the plant needs to handle oxidative stress from strong UV exposure or cold temperatures. The grounding effects of beta-bisabolol tend to work well in strains designed for relaxation in drier regions.


As well caryohyllene is the same my initial thought was correct, humulene is actually alpha caryophyllene:

1. Beta-Caryophyllene (BCP)

  • Aroma/Flavor:
    • Spicy, peppery, sometimes with a hint of clove or cinnamon. BCP gives cannabis its characteristic black pepper scent.
  • Effects:
    • Anti-inflammatory: BCP is unique among terpenes because it binds directly to CB2 receptors in the endocannabinoid system, which makes it a non-psychoactive anti-inflammatory agent.
    • Pain relief: It's commonly used for its analgesic properties, reducing both chronic pain and acute inflammation.
    • Relaxation and stress relief: BCP can also provide calming effects, making it suitable for stress reduction and anxiety management.
  • Environmental Role:
    • Hot, humid environments: BCP plays a crucial role in humid, tropical climates by providing antimicrobial and antifungal properties. It helps plants resist mold and pathogens, which are common in high-moisture environments.
    • It also has insect-repellent qualities, helping plants defend themselves from pests.
  • Common Regions:
    • Found in cannabis strains that thrive in tropical and subtropical climates, or long-flowering varieties that need resistance to fungal infections, such as those in Africa, Southeast Asia, and South America.

2. Humulene (Alpha-Caryophyllene)

  • Aroma/Flavor:
    • Woody, earthy, and slightly bitter. Sometimes described as herbal with pine or forest-like tones. It’s much less spicy than BCP, giving strains a more mellow, earth-driven aroma.
  • Effects:
    • Appetite suppressant: Humulene has been found to have appetite-suppressing effects, similar to THCV, making it useful for individuals looking to manage hunger.
    • Anti-inflammatory: Like BCP, humulene also has anti-inflammatory properties, though it does not bind to the CB2 receptors in the same way. Instead, it provides systemic anti-inflammatory effects.
    • Grounding and relaxing: Humulene contributes to more grounding, calming effects, though it’s not as sedative as some other terpenes. It's more of a subtle, balancing effect.
  • Environmental Role:
    • Dry, arid climates: Humulene is more prevalent in dry or semi-arid regions, where it helps plants manage moisture loss and oxidative stress from intense sunlight or limited water availability. It also provides some antimicrobial benefits, though not as strongly as BCP.
    • It's known for its ability to help plants conserve energy and manage growth under stressful conditions like drought.
  • Common Regions:
    • Humulene is often found in strains from Mediterranean climates, dry highlands, and semi-arid regions, including parts of Central Asia, India, Southern Europe, and Western U.S..

Key Differences:

AspectBeta-Caryophyllene (BCP)Humulene (Alpha-Caryophyllene)
Aroma/FlavorSpicy, peppery, clove, cinnamonWoody, earthy, herbal, pine, slightly bitter
EffectsAnti-inflammatory, pain relief, relaxingAnti-inflammatory, appetite-suppressant, grounding
Receptor ActionBinds to CB2 receptors (non-psychoactive)Does not bind to CB2 receptors
Environmental RoleResists mold, fungi, and pests in humid, tropical climatesManages moisture loss and oxidative stress in dry climates
RegionsHumid, tropical areas (Africa, South America, Southeast Asia)Dry, arid areas (Mediterranean, highlands, semi-arid)

Summary of Differences:

  • BCP is spicier and more common in humid, tropical environments where it helps with antifungal and antimicrobial protection. It has strong anti-inflammatory properties and provides pain relief while also offering stress relief and relaxation.
  • Humulene, on the other hand, is woody and more associated with dry or semi-arid climates, where it helps plants manage water stress. It has appetite-suppressant effects and offers a more subtle grounding and balancing effect compared to BCP.
Both terpenes can coexist in strains, and their combined effects often result in complex terpene profiles that balance spicy and woody characteristics while offering both anti-inflammatory and stress-managing benefits.


Alpha-Ocimene vs. Beta-Ocimene

1. Alpha-Ocimene

  • Aroma/Flavor: Sweet, floral, with herbaceous and sometimes citrus-like notes.
  • Effects: Energizing and uplifting, contributing to a clear-headed and refreshing experience.
  • Environmental Role: Found in low-altitude, humid environments. It helps plants manage high humidity and offers antifungal and antimicrobial protection. Alpha-ocimene is produced by plants that need to fend off mold and mildew in moist climates.
  • Typical Regions: Found in tropical and subtropical areas, such as Southeast Asia, South America, and Africa, where high humidity and moderate sunlight are common.

2. Beta-Ocimene

  • Aroma/Flavor: Spicy, herbal, sometimes with sharper, woody notes.
  • Effects: Still energizing, but more associated with alertness and a sharper mental focus. Some find it to have a slightly more relaxing undertone compared to alpha-ocimene.
  • Environmental Role: Found in drier, hotter environments. Beta-ocimene helps plants deal with heat stress, pests, and oxidative stress from high UV exposure. It is less focused on moisture management and more on protecting against the harsher, drier elements of the environment.
  • Typical Regions: Common in arid, dry climates like Mediterranean, Middle Eastern, and high-altitude regions where sunlight and heat are more intense, and humidity is lower.

Comparison Chart: Alpha-Ocimene vs. Beta-Ocimene

AspectAlpha-OcimeneBeta-Ocimene
Aroma/FlavorSweet, floral, herbaceousSpicy, herbal, with woody notes
EffectsEnergizing, clear-headed, upliftingEnergizing, alert, sometimes slightly relaxing
Environmental RoleAntifungal, antimicrobial in humid environmentsPest resistance, oxidative stress management in dry climates
Typical EnvironmentLow-altitude, humid, tropical/subtropicalHigh-altitude, dry, hot climates
Common RegionsTropical regions like Southeast Asia and AfricaDry, arid regions like Mediterranean, Middle East

Practical Implications in Breeding:

  • Alpha-Ocimene: Best for strains grown in humid climates with high moisture, providing defense against mold and mildew. Suitable for areas with lower UV exposure.
  • Beta-Ocimene: More effective in dry, hot environments where UV exposure and heat stress are more of a concern, offering resilience against pests and oxidative damage.

1. (+)-Terpinolene

  • Aroma/Flavor: Fruity, fresh, citrus, and sometimes piney. Often described as having a more pleasant, uplifting fragrance compared to its counterpart.
  • Effects: Energizing, uplifting, and creative. It can promote a clear-headed, almost euphoric effect without being overstimulating. It’s commonly found in sativa-dominant strains, where it adds to an invigorating and focused experience.
  • Environmental Role: Common in warm, sunny, high-altitude environments with dry climates. It provides plants with UV protection and helps manage oxidative stress from intense sunlight. Additionally, it offers insect-repellent properties.
  • Typical Regions: Found in regions like Mediterranean climates, high-altitude areas, and arid environments, where UV exposure is high, and moisture is low.

2. (–)-Terpinolene

  • Aroma/Flavor: Woody, herbal, earthy, and less fruity. It has a more grounding and heavier aroma, often described as earth-driven with a hint of spice.
  • Effects: Still uplifting, but with more of a calming, centering quality. It promotes a relaxed, focused mental state, but lacks the vibrant, euphoric energy of (+)-terpinolene. Often found in strains that need a balance of alertness and calm.
  • Environmental Role: Common in cooler or higher-altitude environments with moderate UV exposure and higher moisture levels. It helps the plant resist fungal and mildew growth in moist environments and provides some UV protection.
  • Typical Regions: Found in areas with moderate climates, such as temperate forests and subtropical regions, where the climate is mild but not excessively humid.

Comparison Chart: (+)-Terpinolene vs. (–)-Terpinolene

Aspect(+)-Terpinolene(–)-Terpinolene
Aroma/FlavorFruity, fresh, citrus, pineWoody, herbal, earthy, with a hint of spice
EffectsEnergizing, uplifting, creative, euphoricUplifting, but more calming and centering
Environmental RoleUV protection, insect-repellent in dry, sunny areasFungal resistance, UV protection in moist, temperate regions
Typical EnvironmentHigh-altitude, sunny, arid environmentsCooler, moderate-climate regions with some moisture
Common RegionsMediterranean, highlands, arid climatesTemperate forests, subtropical climates

Practical Implications in Breeding:​

  • (+)-Terpinolene: Ideal for strains grown in dry, high-altitude, or sunny environments where UV protection and invigorating effects are desired.
  • (–)-Terpinolene: Better suited for strains grown in moderate, cooler, or humid environments where fungal resistance and a calming effect are needed.
 
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Verdant Whisperer

Well-known member

Linaniol Hypothesis: Uniting Linalool and Geraniol as Functional Partners

Linalool and geraniol are unique among terpenes because they are the only two known terpenes without enantiomeric opposites. Unlike other terpenes like limonene or pinene, which have mirror-image forms (called enantiomers), linalool and geraniol do not exhibit this chiral behavior. This makes them stand out in the terpene world as they exist only in one form. Despite being chemically distinct from each other, they share a molecular weight and are synthesized from similar precursors, giving them similar environmental roles and biological functions.

These two terpenes are best viewed as two expressions within the same terpene family, which I call Linaniol. In this view:

  • Geraniol represents the alpha form (Alpha-Linaniol), and
  • Linalool represents the beta form (Beta-Linaniol).

Why Linalool and Geraniol Are Unique:​

  • No Enantiomers: Unlike limonene (which has R-limonene and S-limonene forms) or pinene (which has alpha and beta forms), linalool and geraniol do not have mirror-image forms. They exist in a singular structural form.
  • Shared Molecular Weight: Both terpenes have the same molecular formula (C10H18O) and the same molecular weight (154.25 g/mol), pointing to their common biosynthetic origins.
  • Similar Environmental Functions: Despite their structural differences, both terpenes serve similar purposes, such as:
    • Attracting pollinators (through their floral aromas),
    • Repelling insects, and
    • Offering antifungal protection.

Introduction to Linaniol: Alpha and Beta Forms:​

The Linaniol Hypothesis suggests that geraniol and linalool represent two functional forms of the same floral terpene family, united by their shared properties and biological roles. Here's how the two expressions differ:


Linaniol Terpene Family Chart:​

CharacteristicAlpha-Linaniol (Geraniol)Beta-Linaniol (Linalool)
Aroma/FlavorSweet, rose-like, floral, citrusy (like geraniums, roses)Soft, lavender-like, floral, with herbal and slightly woody notes
Primary EffectsCalming, uplifting, insect repellent, antifungal, mood-enhancingCalming, relaxing, slightly sedative, antifungal, antibacterial
Typical EnvironmentHumid, tropical, or warm environments where plants need to repel pests and attract pollinatorsFound in both humid and temperate regions, often in herbs that grow in less direct sunlight
Environmental AdaptationHelps plants repel insects and fungi in warm, humid climatesProtects plants in part-shaded, humid environments from fungi and microbial infections
Common SourcesGeraniums, rose oil, lemongrass, citronellaLavender, basil, rosewood, thyme, coriander
Use in CannabisOften found in tropical strains or strains bred for humid environments, promotes floral, sweet aromasCommon in cannabis strains for calming and relaxation, floral-herbal profile
Unique PropertiesKnown for its strong insect-repelling properties, sweet aroma with a citrus twistKnown for its use in aromatherapy to reduce anxiety, stress relief, and minor sedative properties

Revised Linaniol Hypothesis:​

In this updated hypothesis:

  • Alpha-Linaniol (Geraniol) is the sweeter, floral-citrus form, ideal for tropical climates with insect-repelling properties and more uplifting effects.
  • Beta-Linaniol (Linalool) is the lavender-like, floral-herbal form, with relaxing effects, suited for part-shaded or temperate humid environments, where it offers antifungal and calming properties.
By grouping geraniol and linalool as functional partners within the same Linaniol family, we move beyond traditional chemical classification and focus on how these terpenes behave in nature and influence the plants that produce them.
 
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