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Salts, E.C. and Leeching

joe fresh

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With the use of chemical or salt ferts, its important to understand the properties of leeching. For a detailed perspective, do some reading on ion exchange between nutrients and the soil medium. Helps to understand salinity too. Borders, Barnes and Noble have good books.

Basically, some soil components have a high CATION EXCHANGE CAPACITY which allows higher levels of nutrients to adhere to soil particles until dissolved in water for plant uptake. Its kinda like long term storage for nutrients. This is great for slow release or low concentration organics. Or if you water every couple days but only fert every couple weeks.

In this thread, I will focus on underlying strategy OG high dosage-rapid release liquid fertilizers. With these ferts, if you aren’t careful, the salt content can get very high. Even more so if you have low humidity and high evaporation rate. So it would be much safer to use soil components with LOW cation exchange capacity. That simply means that extra nutrients wouldn't be stored as well by the soil...they would just leech out...this would prevent salt buildup (which also limits water uptake) and toxicity which is easy to do with concentrated liquid ferts.

This salt index is a rough barometer of a fertilizer's potential to prevent water absorption from the soil by plant roots....this is in comparison to the potential of an equal weight of Sodium Nitrate, which is therefore given a value of 100. Obviously, a high index has greater chance of freaking your plants! Sodium Nitrate is pretty risky, so if a fert has a rating OVER 100...ya better be darn sure you know what you're doing ;-)

These ferts don't just inhibit water uptake...they actually create a kind of reverse osmosis (i think that's the right term) where water is drawn OUT of the roots!

In general, if you have a fert with a index over 25, be sure to dilute with water...DO NOT apply such ferts right into soil.
Here are a few common ones...I'll see if I can come up with a better list and edit later.

Potassium Chloride-116
Ammonium Nitrate -105
Sodium Nitrate -100
Ureas-75
Potassium Nitrate-74
Ammonium Sulfate 69
Calcium Nitrate-53
Potassium Sulphate-46

I hope I explained that ok.
What's the point? Many growers add Perlite or vermiculite to soil for greater drainage and aeration. USE PERLITE! It has a LOW CEC around 2.0, while vermiculite has anywhere between 85-150!!! In other words, Perlite doesn't 'hold on' to ionic elements....vermiculite 'clings' to them! With Perlite, if you only water once a week or use light doses...you are less likely to accumulate salts leading to toxicity..

This is also key if you want to reuse soil between grows without burning the heck out of seedlings. Usually after a harvest, the soil is LOADED with salts and isn't appropriate for introduction of a newly germinated seedling. Perlite allows a greater capacity for leeching the soil so that it is mild enough to take seedlings.

This is also why you should also leech a plant for the last 2 weeks...no nutes. The plant will use up the majority of nutes in tissues and root area. That way, you have a plant free of excess chemicals when harvested. Much smoother, cleaner, better tasting final product. This is especially important in the case of Nitrogen as it creates a poisonous gas when oxidated....AND it forces the plant to burn at a higher temp which destroys much of the THC before inhaled.

The E.C. value measures the salinity of soil by measuring its conductivity. You want an E.C. under 2.0.....anything around 4.0 needs immediate leeching. There are devices for measuring...honestly, I haven’t bought one because I am pretty comfortable with this....but if you experiment may be worth a look!

Despite my natural aversion for ppm measurement, it would be a good idea when mixing ferts as a beginner. Check your nursery or Home Depot. I've F-ed up a plant or two in my day, always because I THOUGHT I was more accurate with eye measurement than I really was!
 

joe fresh

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TDS, PPM, and EC

TDS, PPM, and EC

TDS, PPM, and EC


If you have any desire to mix your own fertilizers, it is important that you have at least basic understanding of these terms

Electricity is conducted due to the presence of ions (electrically charged) in a solution. The ions get there by introduction of salts via our ferts!

EC (electric conductivity) is a representation of how much potential a solution has to conduct electricity...SO, by testing the ability of a solution to conduct electricity, we can indirectly determine the amount of salts present....thereby knowing if we have the right concentration of ferts.

E.C. is a measure of salinity by measuring its conductivity. You want an E.C. under 2.0.....anything around 4.0 signifies an extreme excess of salt which calls for immediate leeching. There are devices for measuring...honestly, I haven't bought one because I am pretty comfortable with this....but if you experiment may be worth a look!

Despite my natural aversion for ppm measurement, it would be a good idea when mixing ferts as a beginner. Check your nursery or Home Depot. I've F-ed up a plant or two in my day, always because I THOUGHT I was more accurate with eye measurement than I really was!
CF (Conductivity Factor) basically represents the same information but expressed differently. 1 ms/cm is equal to a CF of 10. I don't use this factor and haven't seen many people use it...but just in case, you now have a conversion!

TDS is a measurement, by weight, of the Total Dissolved Solids in a solution and is measured in PPMs (Parts Per Million). Basically, when you hear someone say they introduce nutrients at a rate of 500 PPMs, it means that they have 500 milligrams of solid dissolved in a Liter of water.

You can figure the PPM of your ferts one of two ways.....you can precisely measure the ferts and water you mix together...or you can make a solution and measure the PPM of IT. The shortcut lies in hand-held meters which measure the EC of a solution and then apply mathematical conversion to the EC figure to arrive at PPMs. Keep in mind, even this is an approximate measurement...but plenty accurate for growers!

Some meters actually display the EC AND the PPM readings. Some only express the EC value and this can be tricky because European and American made meters measure at different rates.
An American device that displays an E.C. of 1.0 has 500PPMs.
A European device that displays an E.C. of 1.0 has 640PPMs.
(I believe Australian manufacturers have a different conversion factor also...but not sure.)

So if your American device only displays E.C., use that old algebra and set the two given equations equal to each other. For example, let's say your E.C. reading is 1.2.

Using the known ratio given just above, we'll cross multiply to solve for x to get the unknown ppms.
1.0/500ppm=1.2/x
x=600
Your solution has 600PPMs. (remember, this would be with the American device...a European device would produce a different result!)

If you want to figure out the PPMs yourself, its pretty easy. Each 1 gram of fertilizer per liter of water gives 10PPMs of each given nutrient per percentage point. Sounds clumsy, wish I could state that better....here's an example.

Use 1 gram of SuperPhosphate 0-20-0 in a liter of DISTILLED water. The solution would have 0ppm of N, 200ppm of P, and 0ppm of K. Also keep in mind that tap water already has dissolved solids...most likely anywhere between 200-400 PPMs. Use distilled water when possible...0 PPMs!!

A guideline for NPK strengths
Now, I have seen different parameters for acceptable PPMs. Here is a decent guideline for the N-P-K standards...play around, but make only gradual changes up! Approximate tolerance range of PPMs per nutrient .... most micronutes are tolerated by plants within the same ranges...but the plant just doesn't need nearly that much!

N 200-400
P 200-600
K 200-600

Approximate tolerance range of TOTAL PPMs in soil/medium
(Obviously the plant can tolerate more as it gets larger and has more root area to uptake nutes and leaf area to transpire water.)

Seedling 500-600
Vegetative 800-1000
Flowering 1000-1500
Flushing 500

PPMs for each growth phase
You may desire more N during veg stages for example. The key is NOT to obsess over the exact numbers. Too many experienced growers give advice in exact parameters to appear 'scientific' or something...but there are too many other factors involved in the actual UPTAKE of these nutrients by roots to claim specificity. These are just general parameters that you can tweak under your own conditions. And again, the plant can tolerate more as it gets larger and has more root area to uptake nutes and leaf area to transpire water...start light, gradually increase with each feeding as your lant can handle it.

Keep in mind, my estimates are given for soil mediums which can tolerate higher levels because the soil components will bond with many elemental ions....a hydro system needs to be more precise....I'm not very familiar with those systems. You've read the dislaimer! Also remember that these parameters are based on the assumption of using DISTILLED water. Tap water will add another 200-400 PPMs, so you would have to adjust accordingly...especially with Cl, Ca, Na, and in rare case, S.

SEEDLING (2-3 weeks...look for 4-5 sets of alternating nodes before moving to veg)

N 150
P 100
K 150
Ca 75
Mg 75
S 25-50
Fe 15
Cl 15
Mn 7
Cu 9
Zn 3
Total: 600ppm

VEGETATIVE/PRE-FLOWER (2-4 weeks)

N 300
P 100
K 200
Ca 100
Mg 100
S 50-75
Fe 25
Cl 25
Mn 10
Cu 15
Zn 5
Total: @1000pm

FLOWER (strain dependent-usually 6-8 weeks)

N 300-400
P 400
K 200
Ca 100-150
Mg 100-150
S 100-150
Fe 25+
Cl 25+
Mn 10
Cu 15
Zn 5
Total: @1300-1500ppm

FLUSH/HARVEST (2 weeks)
N 0
P 75
K 75
Ca 50
Mg 50
S 50
Fe 25
Cl 25
Mn 10
Cu 15
Zn 5
Total: @400ppm

I cannot stress enough that these are estimates...conservative ones due to the fact that chemical ferts allow less room for error. In addition, different strains and conditions will result in different ratios....experiment often and use caution always!
 
W

wilbur

thanks for this info! I am learning, learning ... and have just become aware of "Mulder's Chart" re cation/anion interchange. that too much of one mineral will lock out another ...
 
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